Consider the plot of solubility curves in Question 2. For which of the following substances is the sign of ΔHsoln negative?
- ammonium chloride
- cerium sulfate
- potassium chlorate
- sodium nitrate

Consider the plot of solubility curves in Question 2. For which of the following substances is the sign of ΔHsoln negative?

cerium sulfate
Examining the slopes of the given curves:
Therefore, the substance with a negative enthalpy of solution (ΔHsoln) is ammonium chloride (NH4Cl).